I’m wanting to be able to access my Google Drive via Windows 10 Explorer and open, add, edit files in the same was as I can do for One Drive.  Can I do this? And if so, how???

You need to install the Google Drive desktop sync client. See Install Google Drive for Mac/PC – Google Apps Administrator Help. This however, doesn’t Pin Google Drive to the navigation pane. You can do that part manually, but it’s optional anyway. See Pin Google Drive to File Explorer Navigation Pane.